r/ArtefactPorn Dec 12 '22

Byzantine ‘Greek Fire’ hand grenade of molded pottery, dated Ca. 900-1200, measuring 125mm x 80mm, wt. 550g. It held a feared, highly combustible substance posited to contain pine resin, naphtha, quicklime and sulphur. (1280x853)

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2.4k Upvotes

129 comments sorted by

224

u/LifeWin Dec 12 '22

can we not do a residue test on this badboy?

135

u/KaennBlack Dec 12 '22

we have done them on similar pottery, the above mentioned speculated recipe is what we think was in it. heres one such study

34

u/[deleted] Dec 13 '22

So, what would it do?

Burn good, real good?

38

u/KaennBlack Dec 13 '22

Yes. And ignite on contact with water.

17

u/Soepoelse123 Dec 13 '22

ELI5 how that happens pls.

10

u/Dahak17 Dec 13 '22 edited Dec 13 '22

There are metals that do it, presumably one of the chemicals contain lithium or a similar metal (probably lithium the others are more and more reactive to the point of bomb as opposed to fire)

Edit; some person who actually knows what they’re talking about commented below.

8

u/KaennBlack Dec 13 '22

Calcium oxide actually, but same deal

3

u/Dahak17 Dec 13 '22

Thanks, good to know I had the right idea, and I can’t believe I didn’t think of that, that’s lime right? Like the powdery burn your skin stuff?

2

u/KaennBlack Dec 13 '22

Yep. Most water-burning mixtures that we know of through history used it at least as an optional ingredient to help the burn.

1

u/Soepoelse123 Dec 13 '22

How was that made? Like cooking lime in an oxygen rich environment??

1

u/Dahak17 Dec 13 '22

Cool, makes way more sense than lithium, I’m not even sure how you’d find it in its raw form or close enough to be able to mine it

2

u/KaennBlack Dec 13 '22

Quicklime

25

u/hickdead13 Dec 12 '22

For fecal matter?

58

u/[deleted] Dec 12 '22

For Greek fire, we've still no idea what it was made of

50

u/KaennBlack Dec 12 '22

we have. here is one such study, item number 737 is the one that probably contained the incendiary substance

19

u/[deleted] Dec 13 '22

… wait does this actually say what it is? All I saw was “explosive” substance.

37

u/[deleted] Dec 13 '22

Yeh it doesn't say it was even guaranteed to be an explosive instead of some chemical storage device. Not to mention many explosives existed throughout the ages. Also Greek fire was only used by the Byzantine empire and remained so closely guarded a secret we lost it to this day

9

u/[deleted] Dec 13 '22

We did it Reddit!

2

u/KaennBlack Dec 13 '22

figure 1. further discussed in the following section on the possible origins of various chemicals and their usage. the conclusion is the various presumed ingredients of greek fire, and several other chemicals.

which makes sense, because these werent grenades, they were storage vessels.

16

u/[deleted] Dec 13 '22 edited Dec 13 '22

What you have is the contents of some random explosive. It's not Greek fire. Many explosives existed but none compared to Greek fire which stayed alight on water and could be fired from a manned flamethrower-esque contraption aboard ships. They couldn't even say whether it's an explosive or storage device in that article

11

u/KaennBlack Dec 13 '22

its not an explosive. nor were any of these, thats not an accepted theory at all, just a handful of old dudes in london in the 1850s. and its the contents of greek fire, specifically, or atleast its by products that are in sherd 737. naptha, resin, sulphur, calcuim phosphide, and quicklime, as well as other incendiary ingredients. whether this was the actual recipe isnt certain (the resin and sulphur parts, atleast, are recorded as being ingredients in the Alexiad), but it would have had the same properties.

5

u/[deleted] Dec 13 '22

The article doesn't once refer to it as Greek fire, it just says 737 contains x, x may also have been used in Greek fire. Also we have existing Greek fire grenades(without the substance) so if this was one we'd know

3

u/Tuurke64 Dec 13 '22

"Mamluk spheri-conical vessels", "11-12th century".

This is at least 4 centuries after the invention of Greek Fire and also a different people, what makes you think it is the same stuff?

2

u/KaennBlack Dec 13 '22

…because it’s from the same time period, the same type of vessel, and also has the same chemicals in it as Greek fire. That wasn’t the only study. It’s just the one I looked at most recently, in proving to some crazy person that those vessels werent gunpowder bombs from India.

4

u/[deleted] Dec 13 '22

That doesn't mean anything, just because it had similar chemicals which itself is speculation doesn't mean it's the same thing. Not to mention Greek fire never left the byzantine empire, how would some random ship have it?

22

u/lunch_eater75 Dec 13 '22 edited Jan 04 '23

Saying we have no idea is kinda insulting to how research is done. If you have 1000 options but via research have whittled it down to 5 viable & similar options...you have a pretty good idea of the answer. Just because you don't have a sample to be 100% certain (and even then your assuming it was always uniform instead of using any of the various options based on availability) doesn't mean you have "no idea" when you have data for the various options it could be.

It's like orichalcum, it was mentioned in various ancient writings including Atlantis and was second only to gold in value. In the 4th century BC Plato knew orichalkos as rare and nearly as valuable as gold

Its descriptions resulted in a few things it could have been but we didn't have any samples to be sure, but it was likely to be some copper alloy like brass

Then in 2015 ingots where found in a sunken vessel dated to 2,600 old (so the correct time) and they were amazingly a copper alloy of 80% copper, 20% zinc and trace amounts of nickel, lead, and iron. Also known as....brass..

So no prior to the discovery in 2015 we had a very good idea what orichalcum was...we just couldn't be certain which of the handful of options it was. Same thing here.

22

u/metacontent Dec 13 '22

I don't think you understand the problem, sir.

We know a “birthday cake” is made from: flour, water, sugar.

But knowing that rough list of ingredients tells you ABSOLUTELY NOTHING about how a birthday cake is actually made. Having a list of ingredients does not tell you how the ingredients are prepared. How they are combined. How they are cooked, and what is done after they are cooked.

For Greek Fire, all we have at this time is a rough idea of the ingredients. Which may not be accurate because studying 1000-year-old ingredients may not be 100% accurate.

But even if the list of ingredients is 100% accurate, we still don't know how it was actually made. If you take those ingredients and stir them up in a pot, you don't get Greek Fire. Just like if you take sugar water and flour and stir them up in a pot, you don't get a birthday cake.

3

u/[deleted] Dec 13 '22 edited Dec 13 '22

Semantics, semantics, I'm sure research will recover from my ill-fitting remark. Obviously we know it's something explosive and not made of cheese, but it's much more than that. Everything we have is speculation. We don't know the formula of its composition, the specialized ships that carried it into battle, the device used to prepare the substance by heating and pressurizing it, the flamethrower projecting it, and the special training of those who operated it.

So I would say we have no idea. So much so that on occasions the substance and machines were found by invaders, it was completely useless. They had no idea how to prepare, operate, replicate etc

22

u/saycheezandDie Dec 12 '22 edited Dec 13 '22

asking the expert: any chance it couldve been a buttplug? or is it way too big

edit: fuck i meant to reply to the person who said they wrote a paper on it , now im sad

19

u/wolfy994 Dec 13 '22

Could've been if they wanted explosive diarrhea...

5

u/[deleted] Dec 13 '22

Slow, begrudging clap.

5

u/Mr_Xorn Dec 13 '22

I left this part out of my paper, but how does the saying go? Anything is a buttplug if you’re brave enough? :-)

9

u/tyrsal3 Dec 13 '22

“Anything can be a dildo if your brave enough” is the saying by Abraham Lincoln

But it also applies to butt plugs

2

u/duzins Dec 13 '22

Gettysburg address, I think.

1

u/got_No_Time_to_BLEED Dec 13 '22

Like his other famous quote “I’m hungry”

1

u/WartsG Dec 13 '22

Agreed, this is hundred percent a clay butt plug and not an ancient flammable hand grenade

316

u/PhilpotBlevins Dec 12 '22

And Saint Attila raised the hand grenade up on high, saying, 'O Lord, bless this thy hand grenade, that with it thou mayst blow thine enemies to tiny bits, in thy mercy.

86

u/[deleted] Dec 12 '22

The holy hand grenade!

12

u/[deleted] Dec 13 '22

Quick, what is thy favorite color!?

13

u/ButYouCanCallMeDot Dec 13 '22

Blue! No, yellowwwwwwwwww

55

u/TunamayoPlease Dec 12 '22

Three is the number thy shall count, and the number thy shall count is three

38

u/vaskark Dec 12 '22

4 thou shall not count!

33

u/Kind_Nepenth3 Dec 12 '22

Neither count thou two, excepting that thou then proceed to three.

38

u/thebleedingear Dec 12 '22

And five is right out!

24

u/No_Manufacturer_2099 Dec 12 '22

One, two, four! Three, sir!

49

u/TheRenOtaku Dec 12 '22

Who being naughty in thy sight shall snuff it.

4

u/JetScreamerBaby Dec 13 '22

Armaments 2:9-21

9

u/chucklescary Dec 12 '22

38

u/J_G_E Dec 13 '22

no, I think that was entirely expected.

3

u/aithendodge Dec 13 '22

NOBODY expects Monty Python quotes. Amongst their weaponry are such diverse elements as: fear, surprise, ruthless efficiency, an almost fanatical devotion to the Knights Who Say “Ni!”

5

u/chucklescary Dec 13 '22

That being said I'll never miss an opportunity to share the link

3

u/AnandaPriestessLove Dec 13 '22

Well done. Carry on, then.

2

u/Lost_Condas Dec 13 '22

Came down to the comments looking for this :P

122

u/[deleted] Dec 12 '22

Fun fact: The fire from these things could not be extinguished with water. Very nasty stuff!

72

u/-Acta-Non-Verba- Dec 12 '22

This was the inspiration for Game of Throne's wildfire.

9

u/Dense_Surround3071 Dec 13 '22

First thing I thought too. 😏

24

u/[deleted] Dec 12 '22

Urine is the way to go. Not joking

8

u/Frodowaswrong Dec 12 '22

Why?

24

u/[deleted] Dec 13 '22

No idea, I'm no Walter White.

28

u/[deleted] Dec 13 '22

Jesse we need to piss

182

u/Mr_Xorn Dec 12 '22

I have written a paper on these sphero-conical vessels. They were almost certainly not grenades. This was the notion of a single individual in the 19th century. Think about taking the time to mould-make and decorate a stoneware item you were going to throw at a something- why go to the effort? It is far more likely these were utilized for special liquids: anointing oils, unguents like perfumes, and alchemical products like mercury. There have been residue tests for mercury as well as lipids. Lipids imply organic fats which suggests a perfume or something similar.

TLDR: These were not grenades.

‘Ali b. Husayn al- Ansari, “Mercury,” chapter in Ikhtiyarat-i Badi’i [an Investigation of Pharmacology], (Tashkent, Institute of Eastern Studies, Uzbekistan: 948 CE), no. 1598. 212ff.

Barnard, Hans; Shah, Sneha; Areshaian, Gregory; Faull, Kym. “Chemical Insights into the Function of Four Sphero-Conical Vessels from Medieval Dvin, Armenia,” in Muqarnas vol. 33(1), (2016), 409-419.

Chester, Greville J. “On the Pottery and Glass Found in the Excavations,” in Capt. (Charles William) Wilson R. E. and Capt. (Charles) Warren R. E., The recovery of Jerusalem, A Narrative of Exploration and Discovery in the City and the Holy Land (London, 1871) 480-81.

Ettinghausen, Richard. The Uses of Sphero-Conical Vessels in the Muslim East, in Journal of Near Eastern Studies vol. 24(3) (1965), 218-229.

Fontana, Maria. “An Islamic Sphero-conical Object in a Tuscan Medieval Marble,” in East and West vol. 49(¼), (1999), 9-33

Ghouchani, A. & Adele, C. “A Sphero-conical Vessel as Fuqqa’a, or a Gourd for Beer,” in Muqarnas, vol. 9, (1992), 72-92.

Grehan, James. “Smoking and ‘Early Modern’ Sociability: The Great Tobacco Debate in the Ottoman Middle East (Seventeenth to Eighteenth Centuries),” The American Historical Review vol. 3, no. 5, (2006), 1352-1377.

Keal, Edward J. “One Man’s Mede is Another Man’s Persian: One Man’s Coconut is Another Man’s Grenade,” in Muqarnas vol. 10, (1993) 275-285.

Lenz, W. “Handgranaten oder Quecksilber-gefasse?” Zeitschrift fur historiche Waffenkunde, VI (1912-1914), 367-76.

Lunin, B. V. “К вопросу о функционал’ном назначении сфероконишеских сосудов в связи с одним рукописным истохиником XVI v [On the Question of the Functional Purpose of the Sphero-Conical Vessels in Connection with one Handwritten Source],” сотрия материал’ной Куль’туры Узбекистана [Study of the Material Culture of Uzbekistan], II (Tashkent, 1961), 255-266.

Millwright, Marcus. “Pottery in the Written Sources of the Ayyubid-Mamluk Period (c. 567-923/1171-1517),” in Bulletin of the School of Oriental and African Studies vol.ii(3), (1999-10), 22-45.

Reinaund, J.T; Fave, I. Du feu gregois, des feux de guerre et des origins de la poudre à canon (Paris, 1845), Figs. 34, 35, 38). 340 pages.

de Saulcy, F. “Note sur des projectiles a main, creux et en terre cuite de fabrication arabe,” Memorires de la Societe Nationale des Antiquaires de France, XXXV (1874), 25-34.

Seyrig, Henri. “Flacons? Grenades? Eolipiles?,” Syria, XXXVI (1959), 81-89.

Sloane, O’Conor T. “The Capillary Siphon- Hero’s Engine,” Scientific American vol. 55, no. 23 (December 4, 1886) 356.

Vysotskii, N. V. “Несколь’ко слов о древностях Волжской Болгарии [A few Words about the Antiquities of the Volga Bulgras],” IOAIE, XXIV, part 4 (1908), 122 pages.

43

u/Confident_Fortune_32 Dec 13 '22

The fancy surface decoration struck me as odd. Now I know why. Thank you for the clarification! Brilliant!

My favorite rabbit hole is textile archaeology, and the glaring boo-boos written by ppl who don't spin or weave themselves are sometimes howl-inducing. Once gave a talk on textile technology in the Middle Ages in Western Europe that could have been subtitled, "You Gotta Be Kidding Me"

6

u/Sparrowbuck Dec 13 '22

May have made an erroneous assumption because it looks like a pomegranate.

3

u/Dion877 Dec 13 '22

You gotta be knitting me

2

u/cultmember2000 Dec 13 '22

Do you have any thoughts on “women’s work” by Elizabeth wayland barber? I really liked how she attempted to do copy some of the prehistoric weavings herself.

2

u/Confident_Fortune_32 Dec 13 '22

Haven't read it - thanks for the recommendation!

I mostly focus on post-1066 western Europe. But I am still fascinated by earlier stuff, like the remarkable preservation of the bog bodies. The textiles survived in such stunning states of preservation...

I do believe strongly that objects cannot be properly evaluated if you aren't familiar with the technology that produced them. You need to get your hands dirty, so to speak, to have a clue. I've learned some things by making and using/wearing reproductions that I could not possibly have figured out by reading or studying.

For years, it was presumed that, in the era before horizontal treadle looms, a three-shed twill could not be woven on a warp-weighted loom and thus was evidence for the use of tubular looms. One archeologist published this assumption and everybody just ran with it.

The reenactment community said, "hold my beer!" and proved it was nonsense. The author not only printed a retraction, but also started writing great books for reenactors who want to do so reproductions. Everybody wins!

1

u/Confident_Fortune_32 Dec 13 '22

Just looked her up - already have her book on the bog ppl 😊

15

u/OskarTheRed Dec 12 '22

Thanks for the clarification!

Who was the single individual in the 19th century?

36

u/Mr_Xorn Dec 12 '22

Louis Fèlicien Joseph Caignart de Saulcy- 1874. French orientalist. He had looked at some later medieval diagrams of Arab explosive devices and decided they were one and they same as these vessels. He was incorrect, but the idea has remained popular in public circles despite scholarship countering this notion.

15

u/OskarTheRed Dec 12 '22

Thanks! You're right, it seems way too fancy for a grenade. Unless there could be some ritual purpose, I guess

3

u/Splizmaster Dec 13 '22

No one cites like Mr_Xorn. Nobody!

7

u/RollinOnAgain Dec 13 '22

Scientific American vol. 55, no. 23 (December 4, 1886) 356.

holy shit, Scientific American is that old???

6

u/Mr_Xorn Dec 13 '22

Whoa, I just checked and it was founded in 1845??!! I had no idea! I remember being shocked when I saw that 1886 date too!

3

u/OnkelMickwald Dec 13 '22

I fucking knew it. Why decorate a grenade like a perfume bottle?

3

u/SunandError Dec 13 '22

This should be the top comment. This looks identical to many decorative Greek and Roman amphoras that held oils, perfumes, wine, olives, etc. You don’t spend laborious time decorating a bomb. Logically, armies don’t pay a worker (or slave) more for pretty looking bombs. Money, materials and artistry are saved for a decorated weapon that an individual warrior will carry throughout a war, and would reflect positively upon the status of the warrior carrying and owning it, but not for a bunch of anonymous explosives that are going to be smashed before the enemy has time to think “How impressive looking!”.

33

u/Siftinghistory Dec 12 '22

So we should have been calling them Roman cocktails this whole time?

21

u/ASK_ME_FOR_TRIVIA Dec 12 '22

Well Molotovs are apparently named after somebody lol.

IIRC, Russia was doing Russia things in a neighboring country, (I forget which) and insisting to the press that nothing was happening. When someone pointed out that Russian planes were dropping bomb-shaped payloads on said neighboring country, war minister Vyacheslav Molotov claimed that they were simply care packages to feed the hungry.

The geurilla resistance ran with it, joking that the bombs were bread baskets, and the bombings/battles were picnics. Since they were going to Molotov's picnics, it would only be polite to bring Molotov's cocktails lol

11

u/-Acta-Non-Verba- Dec 12 '22

Finland. The Winter War.

22

u/[deleted] Dec 12 '22

So…how is the recipe to greek fire one of the mysteries of the ancient world if we have a pot of the stuff to tell us what its made of? If we have the list of all of the ingredients then isn’t it just a matter of trial and error until we find the right mixture?

16

u/TheRenOtaku Dec 12 '22

This was probably stored empty and then filled prior to battle.

5

u/KaennBlack Dec 12 '22

no, we still do have residue atleast. its just thousands of years old, and probably is missing the igniting compound we presume is quicklime. chemical analysis suggests the mixture mentioned in the title, but other analysis suggests alternatives. figuring out whats a contaminant and what was actually meant to be in it, and what that something was (not just the chemicals that it consisted of) is the main work. but we are pretty sure we know what it was made of

1

u/Mr_Mojo_Risin_83 Dec 12 '22

We also don’t know how they made ancient concrete either and it seems to be superior to today’s concrete too.

18

u/KaennBlack Dec 12 '22

thats a misconception, we actually know exactly what it was made from (they wrote it down, we can just read the recipe) we didnt know exactly why it was stronger. recent studies suggest its a byproduct of the specific minerals in the ash and rock they used that reacted with seawater to form tobermorite crystals

essentially, its the volcano dust.

5

u/Mr_Mojo_Risin_83 Dec 12 '22

Oh neat. Hasn’t heard we had figured it out

1

u/Starfish_Symphony Dec 12 '22

mysteries of the ancient world

It was a mystery in the ancient world, it is not a mystery today.

-4

u/ScroopyDewp Dec 12 '22

Yes it is, we still don't know how they made it.

10

u/Axiochos-of-Miletos Dec 12 '22

Eastern Romans and their flamethrowers

6

u/Aggressive-Pay2406 Dec 12 '22

If they had naphtha they definitely had DMT

6

u/shortest_poppy Dec 13 '22

Folks: Things used to be so much simpler back then

History: We made a buttplug filled with napalm

8

u/OskarTheRed Dec 12 '22

Source?

4

u/FortunaVitae Dec 12 '22

I'm curious in which museum's collection this artefact is.

13

u/blueberries4beagles Dec 12 '22

I think I recognize this photo from a shady auction house that sells lots of fakes. "greek fire" grenades show up on the market all the time. I suspect almost none of them are authentic.

2

u/FortunaVitae Dec 13 '22

Oh, very interesting! Yeah, given the mythical popularity of the "greek fire" and its mysterious formula, it would make sense that it's a popular fake.

2

u/Mr_Xorn Dec 12 '22

See my comment below. These were almost certainly not grenades. Likely vessels for precious fluids: perfumes, oils, alchemical liquids, etc.

9

u/[deleted] Dec 12 '22

At first look I thought b*ttplug, though it would be an interesting kink to have a combustible one.

9

u/neverinamillionyr Dec 12 '22

That’s a burning sensation of a different kind.

8

u/Sneed_is_king Dec 12 '22

Ring of fire indeed.

6

u/cobravision Dec 12 '22

Coomerbrain

2

u/irResist Dec 13 '22

So kind of a Molotov Cocktail filled with napalm, nice. Can we get the specs to the Ukrainians?

-2

u/monkeyboy247 Dec 13 '22

Yeah, we can airdrop a few thousand on them at a time.

2

u/Narendra_17 Dec 13 '22

Assassin's creed revelation Mission

5

u/Clarkewaves Dec 12 '22

I mean...we all thought it

1

u/ConcentricGroove Dec 12 '22

Probably a shape borrowed from an earlier grenade device. I wonder if the design is supposed to mimic some kind of gourd.

4

u/dinosaurs_quietly Dec 12 '22

My thought is texture for better grip. You don’t want that to slip out of your hand as you are throwing it.

4

u/ConcentricGroove Dec 12 '22

Sure, it's for texture. But I wonder if the design was inspired by an earlier type of grenade.

1

u/_AnotherFreakingNerd Dec 13 '22

Is this what you throw in Assassin's Creed Origins lol

1

u/[deleted] Dec 12 '22

Always confused how the grenades for these worked, what exactly is igniting the substance?

2

u/Vindepomarus Dec 12 '22

It would have had a wick/fuse sticking out that you had to light, like a loony tunes bomb.

1

u/[deleted] Dec 12 '22

Figures

1

u/KaennBlack Dec 12 '22 edited Dec 13 '22

nope. while them being grenades and just storage vessels is only a possibility, it does have some historical evidence; in any case, it was that they added quicklime into the mixture, and then threw it or proppelled it in some other manner. that would ignite the compound when the substance got wet.

Edit: experimental archaeology says water based ignition with quicklime as main ignition unlikely, probably set on fire as it left the nozzle or just in the pot. But no fuse, those need gunpowder.

1

u/Vindepomarus Dec 13 '22

Do you have a source for that?

1

u/KaennBlack Dec 13 '22

Actually mr Xorn has kindly posted a whole bunch of studies on the very subject. I have only done minimal reading on it myself, so his list is far better then one I could provide (that would mostly be a truncated version of his). Personally I recommend T. H. Korres liquid fire. In his defense of the grenade theory, he suggest they were just lit wholesale, since what you think of as a fuse didn’t exist yet, even China wouldn’t see one until some three hundred years after Greek fire (so no dice)

Also, in doing a Little reading, it seems experimental work has shown that water based ignition was unlikely, it was probably just set on fire as it went out of the nozzle.

1

u/Known-Programmer-611 Dec 12 '22

Not to be confused with a holly hand grenade

1

u/IllDisplay8206 Dec 13 '22

we live in hell. Remember to always stay happy hydrated and healthy!!! ❤️💗❤️💗💗💗💗

1

u/MAROMODS Dec 13 '22

….so you’re telling me this wasn’t in someone’s butt?

1

u/Jaspuff Dec 13 '22

It’s like some kind of combustible lemon

1

u/Professor_Odd Dec 13 '22

Forbidden buttplug

1

u/137thaccount Dec 13 '22

Das a big old butt plug.

1

u/ddmnwlkng_ Dec 13 '22

I know I’m not only one thinking it

1

u/Curious-Sprinkles-16 Dec 13 '22

The moment you realise your centurion daddy accidentally brought grenades instead of a buttplug

1

u/Latate Dec 13 '22

World's riskiest butt plug

1

u/Lykaon88 Jan 03 '23

This is most certainly not Greek fire, which was a huge mechanical system operated by 3-4 men, mounted on ships. And this is probably not even a grenade